Progress in the field of research on anode materials for lithium-ion batteries

Recently, covid 19 outbreak spreads in Shanghai, China. There are more than 25,000 new asymptomatic domestic infections every day. China is implementing a dynamic zero-out policy. A leading respiratory expert said the key to COVID-19 prevention and control is to minimize transmission and fatality rate. Omicron has a low case fatality rate but is highly transmissible and can still claim many lives in large outbreaks. "Total openness is not applicable in China.  For China, we should keep to the dynamic zero-out and gradually open up."  

However, "dynamic zero clearance" is not the pursuit of complete "zero infection".  As the Novel Coronavirus has its own uniqueness and strong concealment, there may be no way to prevent the detection of cases at present, but rapid detection and prompt treatment must be carried out, as soon as one case is found, one case will be dealt with.  

The situation in Shanghai is serious. As the financial center of China, Shanghai is a very important city, and the outbreak of the epidemic in Shanghai will put a great impact on China's economy.  The current task is to contain the spread of the epidemic as soon as possible, to achieve social zero so that Shanghai's life and economy quickly return to normal.  

As China plays an important role in the global supply chain, the outbreak will have a significant impact on the supply and prices of many Lithium-ion batteries.

Lithium-ion batteries have become hotspots in energy research due to their higher energy density, long service life, and smaller volume compared with lead-acid, nickel-cadmium, nickel-metal hydride, and other batteries, and no memory effect. One. The negative electrode material is one of the critical components of lithium-ion batteries. It acts as the acceptor of lithium ions and realizes the insertion and extraction of lithium ions during the charging and discharging process. Therefore, the quality of the negative electrode material directly affects the overall performance of the lithium-ion battery. Graphite and modified graphite are widely used as anode materials for commercial lithium-ion batteries. Still, their theoretical capacity is only 372mAh/g, which significantly restricts the development of high-energy power batteries. Group IV element (silicon, germanium, tin)-based anode materials have become a research hotspot for next-generation lithium-ion batteries due to their high theoretical capacities (3579mAh/g, 1600mAh/g, 994mAh/g, respectively). However, silicon, germanium, and tin-based anode materials have the problem of significant volume expansion during the charging and discharging process. Long-term charging and discharging will cause the pulverization of particles and the shedding of active materials, thus affecting the cycle stability of lithium-ion batteries.

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In recent years, the advanced lithium-ion battery team led by Han Weiqiang, a researcher at the Institute of New Energy Technology affiliated with the Ningbo Institute of Materials Technology and Engineering, Chinese Academy of Sciences, has made a series of progress in high-capacity silicon, germanium, and tin-based anode materials. In terms of high-performance silicon-based anode materials, researchers have developed a low-cost, high-capacity, and high-stability porous silicon-based anode material technology. By carbon coating, the porous silicon, the performance of the silicon-based negative electrode material for lithium-ion batteries is further improved. The capacity retention rate of the silicon-carbon composite electrode material was 86.8% after 300 charge-discharge cycles. Related research has applied for Chinese invention patents (201410150747.5, 201410276413.2), and the research results were published in NanoEnergy (2015, 11, 490-499) in the form of Communication.

Based on the previous work, the team synthesized and prepared a series of new phase MSn5 (M=Fe, Co, Fe0.5Co0.5) alloy nano-anode materials using the wet chemical method of improving polyols. The synthesized FeSn5 alloy nanoparticles have a theoretical capacity of 929mAhg-1 when used as a negative electrode material for lithium-ion batteries, which is the material with the highest theoretical specific capacity among the reported M-Sn (M is an electrochemically inert metal) alloy. The researchers prepared a series of Fe0.5Co0.5Sn5 new phase alloy nanoparticles with a 30-50nm particle size range, which further expanded the Co-Fe-Sn phase diagram. Related achievements have applied for invention patents (2013104705134, 201310706760X, 2103715406A). At the same time, the charge-discharge mechanism was deeply discussed and explained by in-situ XAFS, in-situ XRD, and electrochemical test methods. The research on the electrochemical mechanism of this series of tin-based new phase alloy anode materials provides effective theoretical guidance for the team's subsequent development of high-performance tin-based anode materials. Relevant results were published in JournalofMaterialsChemistryA (2015, 3(13):7170-7178) and ACS Appl.Mater.Interfaces (2015,7,7912-7919).

The team has also made progress in the research and development of long-life titanium-based anode materials, applying for an invention patent (201310685139. X), and the relevant results were published in the Journal of Materials Chemistry (2014(2), 10599-10606).

High-quality lithium-ion batteries supplier

Luoyang Moon & Star New Energy Technology Co., LTD, founded on October 17, 2008, is a high-tech enterprise committed to developing, producing, processing, selling, and technical services of lithium-ion battery anode materials. After more than 10 years of development, the company has gradually developed into a diversified product structure with natural graphite, artificial graphite, composite graphite, intermediate phase, and other negative materials (silicon-carbon materials, etc.). The products are widely used in high-end lithium-ion digital power and energy storage batteries. If you are looking for Lithium battery anode material, click on the needed products and send us an inquiry:sales@graphite-corp.com.

 


China's non-manufacturing purchasing managers index for March was released by the China Federation of Logistics and Purchasing and the Service Industry Survey Center of the National Bureau of Statistics today. An index of business activity for the non-manufacturing sector as a whole fell below 50 percent. 

 China's non-manufacturing business activity index was 48.4%, down 3.2 percentage points from the previous month. The new orders index was 45.7 percent, down 1.9 percentage points from the previous month, indicating a significant slowdown in the growth of supply and demand in the non-manufacturing sector from the previous month.   In terms of sectors, the business activity index and new order index of transportation, accommodation and catering, culture, sports and entertainment, and tourism-related industries all declined significantly from the previous month. 

Then the Lithium-ion batteries of the market may be affected by significant changes, the price will also be volatile, if you want to know the latest news of the Lithium-ion batteries, welcome to contact us. 

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