What is Manganese Dioxide MnO2 Used For?

Chile's government is considering phasing in a proposed ban on glacial mining to limit projects high in the Andes by some big copper companies. Chile's constitutional assembly has approved a proposal to ban mining in glaciers, protected areas, and areas vital to protecting the country's water system.

Chile's mining minister, Marcela Hernando, said about 20 mines had been identified in protected areas, some close to glaciers, including Codelco's El Teniente and Andina projects and Anglo American Plc's Los Bronces project.

The new measures for glaciers and other protected areas will put about a fifth of Chile's copper MnO2 powder prices are predicted to increase in the next few days.

What is Manganese Dioxide MnO2?
Manganese dioxide is an inorganic compound with the molecular formula MnO2. This black or brown solid is the natural mineral pyrolusite, the main ore of manganese and a constituent of manganese nodules. 
The main use of MnO2 is in dry batteries such as alkaline batteries and zinc-carbon batteries. Manganese dioxide is also used as a pigment and a precursor of other manganese compounds, such as potassium permanganate. It is used as a reagent in organic synthesis, for example, for the oxidation of allyl alcohol. 
 
What is Manganese Dioxide MnO2 Used For? 
Used as a dry cell depolarizer. 
Used as catalysts and oxidants for the synthetic industry. 
Used as colorants, bleaching agents, and iron removal agents for the glass industry and enamel industry.
Used for manufacturing manganese metal, special alloy, ferromanganese castings, gas masks, and electronic materials such as ferrite. 
Used in the rubber industry to increase the viscosity of rubber. 
 
Organic synthetic use:
Manganese dioxide is very useful in organic chemistry. Manganese dioxide is used as an oxide in different forms, because manganese dioxide has multiple crystalline forms, the chemical formula can be written as MnO2·x(H2O) N, where x is between 0 and 0.5, and n can be greater than 0.  Manganese dioxide can be formed from the reactions of potassium permanganate (KMnO4) and Manganese sulphate (MnSO4) at different pH values. 
One chemical reaction specific to manganese dioxide is the conversion of alcohols to aldehydes. Even if the alcohol has a double bond, it will not be oxidized by manganese dioxide: cis-RCH=CHCH2OH + MnO2 → cis-RCH=CHCHO + H2O + MnO 
No matter how active the product is, it doesn't get oxidized again. Diols can be oxidized to dialdehyde by manganese dioxide. Other reactions of manganese dioxide are very many, and can be used in the oxidation of amines, aromatic substances and triols.
 
Laboratory use:
Used as a catalyst for the decomposition of hydrogen peroxide to produce oxygen; Used as a catalyst for the decomposition of potassium chlorate to produce oxygen; Manganese was prepared by aluminothermic reaction with elemental aluminum powder. Used as pigment, yellow glass, etc. Reaction with hot concentrated hydrochloric acid to produce chlorine gas; Reaction with molten potash (potassium hydroxide) in the air to prepare potassium manganate; In the decomposition reaction of potassium permanganate, manganese dioxide acts as self-catalyst of potassium permanganate. 
 
Is MnO2 Explosive? 
It reacts violently with combustible and reductive substances. This creates fire and explosion hazards. 
 
Is Manganese Dioxide Harmful? 
Strong oxidant. Contact with other materials may cause a fire. Harmful by inhalation or swallowing. May cause eye, skin, and respiratory irritation. May cause central nervous system effects. Inhalation of smoke may cause metal smoke fever. According to animal studies, it may cause adverse reproductive effects.
 
MnO2 Price
The price is influenced by many factors including the supply and demand in the market, industry trends, economic activity, market sentiment, and unexpected events.
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MnO2 Supplier
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New Delhi: India's Oil Ministry recently conveyed its intention to five national oil companies including Indian Oil Corp and Bharat Petroleum Resources LTD to assess the possibility of buying shares in Russian oil projects sold by European and American oil majors.  

Bp announced it would give up its 19.75% stake in Rosneft, the Russian oil company.  ExxonMobil said on March 1 that it would exit about $4 billion in assets and terminate all of its Russian operations, including the Sakhalin-1 project in Russia's far East.  

India's oil ministry has asked the overseas investment arm of India's Oil and Gas Corporation to consider buying ExxonMobil's 30 percent stake in the Sakhalin 1 project in Russia's far East. ExxonMobil is the operator of the project and Indian companies already have a 20 percent stake in the project.

Because of the ever-changing international situation, the supply and prices of international bulk MnO2 powder are still very uncertain.

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